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名   称 Understanding pore evolution in a lacustrine calcareous shale reservoir in the oil window by pyrolyzing artificial samples in a semi-closed system
科技资源标识 CSTR:11738.14.NCDC.XDA14.PP4386.2024
DOI 10.1016/j.petrol.2020.108230
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摘   要 Calcareous shale is a favorable target for shale oil exploration, because shale oil moves more easily in calcareous
shale than in clay-rich shale and the high carbonate content is beneficial to shale fracturing. Although shale oil
exploration has been undertaken successfully in marine carbonate-rich shale (e.g., the Eagle Ford shale) in the
USA, no major breakthrough has yet been made considering lacustrine calcareous shale. The lack of under-
standing pore evolution in lacustrine calcareous shale increases exploration risk. Thus, an integrated analysis
(Rock-Eval pyrolysis, X-ray diffraction (XRD1), low-pressure gas adsorption, field emission scanning electron
microscopy (FE-SEM2), energy dispersive X-ray spectroscopy (EDS3), and helium pycnometry) of lacustrine
calcareous shale from the Lucaogou Formation in the Santanghu Basin and of pyrolyzed shale was undertaken to
document the hydrocarbon generation and expulsion, oil bearing capacity, and evolution of pores in the oil
window. The thermal stress was calculated as the vitrinite reflectance equivalent (%Re4) based on the Easy%Ro
method. The experimental results showed that the residual oil content and oil saturation index (OSI5) increased
with increasing maturity at 0.6–1.29 %Re. The clogging of pores by generated oil and intense compaction caused
a decrease in the volume of mesopores and macropores at 0.79–1.2 %Re, while abundant organic matter (OM6)
pores formed due to hydrocarbon generation and expulsion at 1.29 %Re. Micron-scale dissolution pores and
shrinkage OM pores contributed considerably to the total porosity, which improved the performance of the
lacustrine calcareous shale reservoir at 1.0–1.29 %Re. Accordingly, the maturity range of 1.2–1.29 %Re is
favorable for shale oil exploration in lacustrine calcareous shale due to the high OSI and the widely developed
dissolution pores and shrinkage OM pores.
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关键词
作者 Wang Taoli
数据量 23.6 MiB
论文类型: journal
论文网址: https://doi.org/10.1016/j.petrol.2020.108230
期刊名称: Journal of Petroleum Science and Engineering
出版时间: 2021-05-01
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数据引用
Wang Taoli. Understanding pore evolution in a lacustrine calcareous shale reservoir in the oil window by pyrolyzing artificial samples in a semi-closed system. 国家冰川冻土沙漠科学数据中心(http://www.ncdc.ac.cn), 2024. https://cstr.cn/CSTR:11738.14.NCDC.XDA14.PP4386.2024.
Wang Taoli. Understanding pore evolution in a lacustrine calcareous shale reservoir in the oil window by pyrolyzing artificial samples in a semi-closed system. 国家冰川冻土沙漠科学数据中心(http://www.ncdc.ac.cn), 2024. https://www.doi.org/10.1016/j.petrol.2020.108230.
许可协议
知识共享许可协议   本作品采用 知识共享署名 4.0 国际许可协议进行许可。

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